Never URLs/URL Rules are only used by the LastPass browser extensions. The mobile apps have their own settings, for Android it's in the menu > Settings > AutoFill > App settings (but that's based on an apps, and can skip certain apps from autofilling, and doesn't work for specific URLs on Android.)
Our developers do have a feature request to add support for URL Rules to the Android app, although we do not currently have any news for if or when this would be added to the app.
RachelO is a member of the LogMeIn Community Care Team.
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